Isoskeletal Schiff base polynuclear coordination clusters: synthetic and theoretical aspects

Griffiths, Kieran, Dokorou, Vassiliki N, Spencer, John, Abdul-Sada, Alaa, Vargas, Alfredo and Kostakis, George E (2016) Isoskeletal Schiff base polynuclear coordination clusters: synthetic and theoretical aspects. CrystEngComm, 18 (5). pp. 704-713. ISSN 1466-8033

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Abstract

This work addresses and enlightens synthetic aspects derived from our effort to systematically construct isoskeletal tetranuclear coordination clusters (CCs) of the general formula [TR2Ln2(LX)4(NO3)2(solv)2] possessing a specific defected dicubane topology, utilizing various substituted Schiff base organic ligands (H2LX) and NiII/CoII and Dy(OTf)3 salts. Our synthetic work is further supported by DFT studies.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry
Depositing User: Alfredo Vargas
Date Deposited: 27 Jan 2016 12:19
Last Modified: 06 Mar 2017 10:26
URI: http://sro.sussex.ac.uk/id/eprint/59436

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Project NameSussex Project NumberFunderFunder Ref
Defect dicubane 3d/Dy(III) Coordination Clusters: Heading for materials displaying catalytic propertiesG1632EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCILEP/M023834/1