Mizoroki–Heck reactions catalysed by (N-heterocyclic carbene)PdCl2(Et3N) complexes

Gallop, Christopher W D, Zinser, Caroline, Guest, Daniel and Navarro, Oscar (2014) Mizoroki–Heck reactions catalysed by (N-heterocyclic carbene)PdCl2(Et3N) complexes. Synlett, 25 (15). pp. 2225-2228. ISSN 0936-5214

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Abstract

Complexes of general formula (NHC)PdCl2(Et3N) were used as pre-catalysts in Mirozoki–Heck couplings of activated aryl chlorides and deactivated aryl bromides as electrophiles, without the need of an inert atmosphere and in relatively short reaction times. The protocol was extended to the use of microwave heating, reducing further the reaction times with no detriment in the yields of the desired products.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry > QD0241 Organic chemistry
Depositing User: Oscar Navarro Fernandez
Date Deposited: 02 Jun 2015 12:09
Last Modified: 02 Jun 2015 12:09
URI: http://sro.sussex.ac.uk/id/eprint/54247
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