β-diketiminato organolead complexes: structures,207Pb NMR, and Hammett correlations

Taylor, Morgan J, Coakley, Emma J, Coles, Martyn P, Cox, Hazel and Fulton, J Robin (2015) β-diketiminato organolead complexes: structures,207Pb NMR, and Hammett correlations. Organometallics, 34 (11). pp. 2515-2521. ISSN 0276-7333

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Abstract

The synthesis, structure, and spectroscopic details of a series of β-diketiminato lead(II) alkyl complexes are described. The Hammett correlation between the 207Pb NMR chemical shifts and σpara Hammett constant was examined computationally and found to be due to the paramagnetic shielding contribution, whereas the diamagnetic and spin–orbit coupling contributions remained fairly constant across this series of compounds.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Hazel Cox
Date Deposited: 07 May 2015 08:19
Last Modified: 24 Sep 2015 13:56
URI: http://sro.sussex.ac.uk/id/eprint/53887
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