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ß-diketiminato organolead complexes: structures,207Pb NMR, and Hammett correlations

journal contribution
posted on 2023-06-08, 20:42 authored by Morgan J Taylor, Emma J Coakley, Martyn P Coles, Hazel CoxHazel Cox, J Robin Fulton
The synthesis, structure, and spectroscopic details of a series of ß-diketiminato lead(II) alkyl complexes are described. The Hammett correlation between the 207Pb NMR chemical shifts and spara Hammett constant was examined computationally and found to be due to the paramagnetic shielding contribution, whereas the diamagnetic and spin–orbit coupling contributions remained fairly constant across this series of compounds.

History

Publication status

  • Published

Journal

Organometallics

ISSN

0276-7333

Publisher

American Chemical Society

Issue

11

Volume

34

Page range

2515-2521

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2015-05-07

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