Multiple complexation of CO and related ligands to a main group element

Braunschweig, Holger, Dewhurst, Rian D, Hupp, Florian, Nutz, Marco, Radacki, Krzysztof, Tate, Christopher W, Vargas, Alfredo and Ye, Qing (2015) Multiple complexation of CO and related ligands to a main group element. Nature, 522. pp. 327-330. ISSN 0028-0836

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Abstract

The ability of an atom or molecular fragment to bind multiple carbon monoxide (CO) molecules to form multicarbonyl adducts is a fundamental trait of transition metals. Transition-metal carbonyl complexes are vital to industry, appear naturally in the active sites of a number of enzymes (such as hydrogenases), are promising therapeutic agents, and have even been observed in interstellar dust clouds2. Despite the wealth of established transition-metal multicarbonyl complexes3, no elements outside groups 4 to 12 of the periodic table have yet been shown to react directly with two or more CO units to form stable multicarbonyl adducts. Here we present the synthesis of a borylene dicarbonyl complex, the first multicarbonyl complex of a main-group element prepared using CO. The compound is additionally stable towards ambient air and moisture. The synthetic strategy used—liberation of a borylene ligand from a transition metal using donor ligands—is broadly applicable, leading to a number of unprecedented monovalent boron species with different Lewis basic groups. The similarity of these compounds to conventional transition-metal carbonyl complexes is demonstrated by photolytic liberation of CO and subsequent intramolecular carbon–carbon bond activation.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry
Depositing User: Alfredo Vargas
Date Deposited: 22 Jun 2015 06:32
Last Modified: 22 Jun 2015 06:32
URI: http://sro.sussex.ac.uk/id/eprint/53701
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