A magnetically highly frustrated CuII27 coordination cluster containing a Cu18 folded-sheet motif

Kühne, Irina A, Kostakis, George E, Anson, Christopher E and Powell, Annie K (2015) A magnetically highly frustrated CuII27 coordination cluster containing a Cu18 folded-sheet motif. Chemical Communications, 51 (13). pp. 2702-2705. ISSN 1359-7345

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Abstract

[CuII27(μ4-O)2(OH)13(OMe)7(vanox)10(NO3)8(OH2)2(MeOH)7](NO3)2·2H2O·11MeOH (1) was synthesised from Cu(NO3)2·3H2O and o-vanillin-oxime. Structural analysis shows a molecule composed of a Cu18 “folded-sheet” motif linked to a Cu9 bridging unit. The cluster is highly frustrated and has an S = 1/2 spin ground state.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry
Depositing User: Tom Gittoes
Date Deposited: 10 Mar 2015 10:34
Last Modified: 10 Mar 2015 10:34
URI: http://sro.sussex.ac.uk/id/eprint/53293
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