Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex

Kilpatrick, Alexander F R and Cloke, F Geoffrey N (2014) Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex. Chemical Communications, 50. pp. 2769-2771. ISSN 1359-7345

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Abstract

The bimetallic bis(pentalene) complex (μ:η5,η5-Pn†)2Ti2 reductively splits CO2 to form a bis(oxo) bridged dimer [(η8-Pn†)Ti(μ-O)]2, in which the Ti–Ti bond has been cleaved, and the dicarbonyl complex (μ:η5,η5-Pn†)2[Ti(CO)]2.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry
Depositing User: Tom Gittoes
Date Deposited: 09 Mar 2015 10:22
Last Modified: 09 Mar 2015 10:22
URI: http://sro.sussex.ac.uk/id/eprint/53231
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