Fe(III)/Cu(II) mediated 5- and 6-exo oxidative ring expansion/cyclisation of cyclopropyl ethers: studies towards dictyol C and α-eudesmol

Booker-Milburn, Kevin I, Cox, Brian, Grady, Mick, Halley, Frank and Marrison, Shaun (2000) Fe(III)/Cu(II) mediated 5- and 6-exo oxidative ring expansion/cyclisation of cyclopropyl ethers: studies towards dictyol C and α-eudesmol. Tetrahedron Letters, 41 (23). pp. 4651-4655. ISSN 0040-4039

Full text not available from this repository.

Abstract

The outcome of oxidative ring expansion/cyclisation of cyclopropanes with a mixed Fe(III)/Cu(II) system was found to be dependent on the mode of cyclisation. When 6-exo cyclisation was attempted unusual products resulting from oxidation of ring opened primary radicals were obtained.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry
Depositing User: Tom Gittoes
Date Deposited: 13 Jan 2015 12:07
Last Modified: 13 Jan 2015 12:07
URI: http://sro.sussex.ac.uk/id/eprint/52066
📧 Request an update