Ritter type reactions of N-Chlorosaccharin: a method for the electrophilic diamination of alkenes

Booker-Milburn, Kevin I, Guly, Dominic J, Cox, Brian and Procopiou, Panayiotis A (2003) Ritter type reactions of N-Chlorosaccharin: a method for the electrophilic diamination of alkenes. Organic Letters, 5 (18). pp. 3313-3315. ISSN 1523-7060

Full text not available from this repository.

Abstract

N-Chlorosaccharin has been shown to undergo electrophilic Ritter-type reactions with alkenes in acetonitrile. The resulting labile β-chloro sulfonylamidines can be ring-opened and cyclized to imidazolines. Overall this provides a one pot method for the electrophilic diamination of alkenes. Competing aziridine formation as well as allylic chlorination are also observed depending on the nature of the alkene used.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry
Depositing User: Tom Gittoes
Date Deposited: 13 Jan 2015 10:44
Last Modified: 13 Jan 2015 10:44
URI: http://sro.sussex.ac.uk/id/eprint/52059
📧 Request an update