Olefin cross-metathesis/Suzuki–Miyaura reactions on vinylphenylboronic acid pinacol esters

Baltus, Christine B, Chuckowree, Irina S, Press, Neil J, Day, Iain J, Coles, Simon J, Tizzard, Graham J and Spencer, John (2013) Olefin cross-metathesis/Suzuki–Miyaura reactions on vinylphenylboronic acid pinacol esters. Tetrahedron Letters, 54 (10). pp. 1211-1217. ISSN 0040-4039

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Abstract

A series of alkenyl phenylboronic acid pinacol esters has been synthesized via an olefin cross-metathesis reaction of vinylphenylboronic acid pinacol ester derivatives. After catalytic hydrogenation, the resulting boronates were coupled via a microwave-mediated Suzuki–Miyaura reaction to afford a library of biarylethyl aryl and biarylethyl cycloalkyl derivatives. A complementary reaction sequence involved an initial Suzuki–Miyaura coupling.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science
Depositing User: Deeptima Massey
Date Deposited: 30 Sep 2014 11:27
Last Modified: 30 Sep 2014 11:27
URI: http://sro.sussex.ac.uk/id/eprint/50421
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