Complete and partial 1,2-additions across transition metal-boron double bonds

Braunschweig, Holger, Ye, Qing, Vargas, Alfredo, Dewhurst, Rian D and Hupp, Florian (2014) Complete and partial 1,2-additions across transition metal-boron double bonds. Journal of the American Chemical Society. ISSN 1520-5126

Full text not available from this repository.

Abstract

The first 1,2-additions across a metal-boron double bond are reported, one a definitive chlorogallation of a Fe=B bond, the other a partial chlorogallation of a Mo=B bond that leads to a highly unusual, planar Mo-B-Ga-Cl rhombus. The two reactions occur with opposite regiochemistry, with the Ga atom bound to the Fe atom in the former and to both the Mo and B atoms in the latter. The bonding in the Mo adduct, as well as the reasons for the differing regiochemistry of the reaction, are explored computationally.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry
Depositing User: Alfredo Vargas
Date Deposited: 25 Jun 2014 10:32
Last Modified: 25 Jun 2014 13:42
URI: http://sro.sussex.ac.uk/id/eprint/49063
📧 Request an update