Synthesis and electronic structure of the first cyaphide-alkynyl complexes

Trathen, Nicola, Leech, Matthew C, Crossley, Ian R, Greenacre, Victoria K and Roe, S Mark (2014) Synthesis and electronic structure of the first cyaphide-alkynyl complexes. Dalton Transactions, 43 (24). pp. 9004-9007. ISSN 1477-9226

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Abstract

The novel complexes trans-[Ru(dppe)2(CCR)(CP)] (R = CO2Me,
C6H4OMe), the first to incorporate cyaphide as part of a conjugated system, are obtained in facile manner. The electronic structure of these compounds is probed by X-ray, DFT and UV/Vis studies.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry > QD0146 Inorganic chemistry
Depositing User: Ian Crossley
Date Deposited: 02 Jun 2014 08:34
Last Modified: 02 Jun 2014 08:34
URI: http://sro.sussex.ac.uk/id/eprint/48848
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