Characterization and orientation of adsorbed NO dimers on Ag{111} at low temperatures

Brown, W A, Gardner, P, Perez Jigato, M and King, D A (1995) Characterization and orientation of adsorbed NO dimers on Ag{111} at low temperatures. Journal of Chemical Physics, 102 (18). 7277 - 7280. ISSN 0021-9606

Full text not available from this repository.

Abstract

Reflection‐absorption infrared spectroscopy (RAIRS) and near‐edge x‐ray absorption fine structure(NEXAFS) have been used, with isotopic 14NO/15NO mixtures, to determine the structure and orientation of the monolayer species formed by NO adsorption on Ag{111} at 40 to 60 K. The adlayer is composed of NO dimers bonded with the N–N axis in the surface plane and with the molecular plane tilted away from the surface normal by about 30°. This structure provides a simple basis for understanding the facile reaction to adsorbed N2O and O which occurs on heating to 70 to 90 K.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science
Depositing User: Deeptima Massey
Date Deposited: 22 Jul 2014 09:36
Last Modified: 22 Jul 2014 09:36
URI: http://sro.sussex.ac.uk/id/eprint/48655
📧 Request an update