File(s) not publicly available
Characterization and orientation of adsorbed NO dimers on Ag{111} at low temperatures
journal contribution
posted on 2023-06-08, 17:17 authored by Wendy BrownWendy Brown, P Gardner, M Perez Jigato, D A KingReflection-absorption infrared spectroscopy (RAIRS) and near-edge x-ray absorption fine structure(NEXAFS) have been used, with isotopic 14NO/15NO mixtures, to determine the structure and orientation of the monolayer species formed by NO adsorption on Ag{111} at 40 to 60 K. The adlayer is composed of NO dimers bonded with the N–N axis in the surface plane and with the molecular plane tilted away from the surface normal by about 30°. This structure provides a simple basis for understanding the facile reaction to adsorbed N2O and O which occurs on heating to 70 to 90 K.
History
Publication status
- Published
Journal
Journal of Chemical PhysicsISSN
0021-9606Publisher
American Institute of PhysicsExternal DOI
Issue
18Volume
102Page range
7277 - 7280Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2014-07-22Usage metrics
Categories
No categories selectedKeywords
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC