Strained ansa half-sandwich complexes of ruthenium and osmium and a non-iron metallopolymer by ring-opening polymerization

Braunschweig, Holger, Dellermann, Theresa, Dewhurst, Rian D, Mies, Jan, Radacki, Krzysztof, Stellwag-Konertz, Sascha and Vargas, Alfredo (2014) Strained ansa half-sandwich complexes of ruthenium and osmium and a non-iron metallopolymer by ring-opening polymerization. Organometallics, 33 (7). pp. 1536-1539. ISSN 1520-6041

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Abstract

Herein we report the first non-iron polymer obtained from an ansa half-sandwich complex. This polymeric organometallic material was obtained from a new disilanediyl-bridged ruthenium complex upon thermally induced ring-opening polymerization (ROP). Additionally, a corresponding distannanediyl-bridged osmium species is reported, the first example of an ansa half-sandwich complex of this element.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry
Depositing User: Alfredo Vargas
Date Deposited: 01 Apr 2014 17:16
Last Modified: 14 Aug 2014 12:57
URI: http://sro.sussex.ac.uk/id/eprint/47872
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