Insights into the mechanism for gold catalysis: behaviour of gold(i) amide complexes in solution

Bobin, Mariusz, Day, Iain J, Roe, Stephen M and Viseux, Eddy M E (2013) Insights into the mechanism for gold catalysis: behaviour of gold(i) amide complexes in solution. Dalton Transactions, 42 (18). pp. 6592-6602. ISSN 1477-9226

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Abstract

We report the synthesis and activity of new mononuclear and dinuclear gold amide complexes . The dinuclear complexes and were characterised by single crystal X-ray analysis. We also report solution NMR and freezing point depression experiments to rationalise their behaviour in solution and question the de-ligation process invoked in gold catalysis.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science
Q Science > QD Chemistry
Q Science > QD Chemistry > QD0071 Analytical chemistry
Q Science > QD Chemistry > QD0146 Inorganic chemistry
Q Science > QD Chemistry > QD0241 Organic chemistry
Q Science > QD Chemistry > QD0450 Physical and theoretical chemistry
R Medicine > RC Internal medicine > RC0254 Neoplasms. Tumors. Oncology Including cancer and carcinogens
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Depositing User: Deeptima Massey
Date Deposited: 20 Mar 2013 11:10
Last Modified: 07 Mar 2017 11:07
URI: http://sro.sussex.ac.uk/id/eprint/44093

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