Confirming the existence of π-allyl-palladium intermediates during the reaction of meta photocycloadducts with palladium(ii) compounds

Penkett, Clive S, Brann, Paul J, Woolford, Jason A and Kahan, Rachel J (2013) Confirming the existence of π-allyl-palladium intermediates during the reaction of meta photocycloadducts with palladium(ii) compounds. Chemical Communications, 49 (11). pp. 1106-1108. ISSN 1359-7345

[img]
Preview
PDF - Published Version
Download (1MB) | Preview

Abstract

The transient existence of π-allyl-palladium intermediates formed by the reaction of Pd(OAc)2 and anisole-derived meta photocycloadducts has been demonstrated using NMR techniques. The intermediates tended to be short-lived and underwent rapid reductive elimination of palladium metal to form allylic acetates, however this degradation process could be delayed by changing the reaction solvent from acetonitrile to chloroform.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry
Depositing User: Rachel Kahan
Date Deposited: 27 Feb 2013 11:49
Last Modified: 07 Mar 2017 07:12
URI: http://sro.sussex.ac.uk/id/eprint/43835

View download statistics for this item

📧 Request an update