Bis(methimazolyl)borate chemistry of palladium and platinum

Crossley, Ian R and Hayes, Jack (2012) Bis(methimazolyl)borate chemistry of palladium and platinum. Journal of Orgnometallic Chemistry, 716. pp. 285-288. ISSN 0022-328X

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Abstract

The complexes [Pd{κ2-S,S′-H2B(mimMe)2}(η3-C3H4R)] (R = H, Me) have been obtained in high yield from the dichloromethane mediated reaction of the respective [Pd(Cl)(η3-C3H4R)] with K[H2B(mimMe)2]. Attempts to prepare analogous compounds of platinum have led instead to the observation of species consistent with incidences of B–H activation, including the unexpected and facile formation of [PtH(PPh3){κ4-B(mimMe)3}]Cl.

Item Type: Article
Additional Information: Online First Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry > QD0146 Inorganic chemistry
Depositing User: Ian Crossley
Date Deposited: 13 Aug 2012 08:35
Last Modified: 13 Aug 2012 08:35
URI: http://sro.sussex.ac.uk/id/eprint/40360
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