Facile self-assembly of the first diphosphametacyclophane

Saunders, Amy J, Crossley, Ian R, Coles, Martyn P and Roe, S Mark (2012) Facile self-assembly of the first diphosphametacyclophane. Chemical Communications, 48. pp. 5766-5768. ISSN 1359-7345

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Abstract

The reaction of isophthaloyl chloride and methyl-bis(trimethylsilyl)phosphane under mild conditions affords high yields of m-{-C(O)-C6H4(C(O)PMe)}2 (1,10-dimethyl-1,10-diphospha-[3.3]-metacyclophane-2,9,11,18-tetraone): the first example of a diphosphametacyclophane.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry
Q Science > QD Chemistry > QD0146 Inorganic chemistry
Depositing User: Ian Crossley
Date Deposited: 21 May 2012 08:34
Last Modified: 21 May 2012 08:34
URI: http://sro.sussex.ac.uk/id/eprint/39361
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