Variable coordination chemistry of the phospha(III)guanidinate anion; application as a metal-functionalised phosphine ligand

Coles, Martyn and Hitchcock, Peter (2002) Variable coordination chemistry of the phospha(III)guanidinate anion; application as a metal-functionalised phosphine ligand. Chemical Communications, - (23). pp. 2794-2795. ISSN 1359-7345

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Abstract

Structural investigation of Li-complexes of the phospha(III)-guanidinate anion [Ph2PC{(NPr)-Pr-i}(2)](-) revealed variable coordination to lithium; synthesis of the dimethyl aluminium compound, (Ph2PC{(NPr)-Pr-i}(2))AlMe2, which behaves as a metal-functionalised phosphine ligand towards platinum, is reported.

Item Type: Article
Additional Information: MPC conducted all synthetic work and is the corresponding author. The first study of different bonding modes of the phosphaguanidinate anion within lithium complexes. A new class of metal functionalized phosphine ligand incorporated into a hetero-trimetallic complex.
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Martyn Coles
Date Deposited: 06 Feb 2012 21:26
Last Modified: 30 Mar 2012 11:16
URI: http://sro.sussex.ac.uk/id/eprint/31223
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