Novel routes to the kainates: Stereoselectivity in addition reactions to pyrrole [1,2c]-oxazol-3-one

Murray, A J, Parsons, P J, Greenwood, E S and Viseux, E M E (2004) Novel routes to the kainates: Stereoselectivity in addition reactions to pyrrole [1,2c]-oxazol-3-one. SYNLETT, 2004 (9). pp. 1589-1591. ISSN 0936-5214

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Abstract

This paper describes the addition of a range of electrophiles to 1. An unusual and unpredicted stereochemistry of addition has been observed in line with our original photochemical observations

Item Type: Article
Additional Information: EMEV did much of synthetic work, the computer based calculations and is principle author. This paper features a relevant discussion for the observation of the unexpected diastereocontrol during electrophilic additions on bicyclic 2,5-dihydro-1H-pyrroles, and presents theoretical calculations in an attempt to rationalise this outcome.
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Philip Parsons
Date Deposited: 06 Feb 2012 21:21
Last Modified: 30 Mar 2012 09:26
URI: http://sro.sussex.ac.uk/id/eprint/30891
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