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Single crystal X-ray structure of tetrahedral C60F36: the most aromatic and distorted fullerene
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posted on 2023-06-08, 09:39 authored by Peter Hitchcock, Roger TaylorTetrahedral C60F36 is shown by its single-crystal X-ray structure to be the most aromatic (and distorted) fullerene derivative, having four planar hexagons with almost equal bond lengths, the average of which (1.373 Å) is the same as in C60F18; one exceptionally long FC–CF bond (1.665 Å) corresponds to the similarly long bond in C60F18 (a motif of T C60F36) and is likely to be the site of oxygen insertion in C60F36O.
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Publication status
- Published
Journal
Chemical CommunicationsISSN
1359-7345Publisher
Royal Society of ChemistryExternal DOI
Issue
18Volume
18Page range
2078-2079Pages
2.0Department affiliated with
- Chemistry Publications
Notes
PH co-authored the paper and solved the structure of this aromatic but very disordered fullerene, all authors are from Sussex, cited 32 timesFull text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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