Transformation of Coordinated Dinitrogen by Reaction with Dihydrogen and Primary Silanes

Fryzuk, Michael D, Love, Jason B, Rettig, Steven J and Young, Victor G Jr (1997) Transformation of Coordinated Dinitrogen by Reaction with Dihydrogen and Primary Silanes. Science, 275. 1445 - 1447. ISSN 0036-8075

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Abstract

The reaction of dihydrogen with a side-on bound dinitrogen complex of zirconium was
investigated. Instead of a displacement of the dinitrogen moiety, which is the common
mode of reactivity, a complex containing both a bridging hydride and a bridging hydrazido unit with a nitrogen-hydrogen bond was observed. This reaction was extended
to primary silanes to produce a species that contained a nitrogen-silicon bond. In
addition, an intermediate in the dihydrogen addition has been structurally characterized
as having a bridging dihydrogen unit

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: EPrints Services
Date Deposited: 06 Feb 2012 21:12
Last Modified: 23 Jul 2013 14:23
URI: http://sro.sussex.ac.uk/id/eprint/30237
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