Further Investigations of the A <- X transition of the Kr.NO and Xe.NO complexes using (1+1) REMPI spectroscopy

Gamblin, Stuart D, Daire, Sophia E, Lozeille, Jerome and Wright, Timothy G (2000) Further Investigations of the A <- X transition of the Kr.NO and Xe.NO complexes using (1+1) REMPI spectroscopy. Chemical Physics Letters, 325 (1-3). 232 - 240. ISSN 0009-2614

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Abstract

The Ã←X̃ transitions of the KNO and XNO molecular complexes have been recorded with improved quality. In both cases the origin band consists of a single feature, consistent with a (near) linear à state. The spectra demonstrate a wealth of structure, which increases in complexity to higher energy; this is interpreted in terms of a weakening of the interaction as the internal energy increases. Dissociation energies for both the X̃ and à states are derived. Attempts to record the corresponding spectra for NNO were unsuccessful. The trend in the binding energies in the X̃ and à states of RNO (Rg=He–Xe) is discussed.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: EPrints Services
Date Deposited: 06 Feb 2012 21:02
Last Modified: 24 Jul 2013 14:14
URI: http://sro.sussex.ac.uk/id/eprint/29275
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