Synthesis and reactivity of tin amide complexes

Harris, Lisa A-M, Coles, Martyn P and Fulton, J Robin (2011) Synthesis and reactivity of tin amide complexes. Inorganica Chimica Acta, 369 (1). pp. 97-102. ISSN 00201693

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Abstract

A terminal tin amide and a terminal tin anilide complex, (BDI)SnN(iPr 2) and (BDI)SnN(H)Ar (Ar = 2,6-iPr2C 6H3), respectively, have been synthesized utilizing the bulky ß-diketiminate ligand, [{N(2,6-iPr2C 6H3)C(Me)}2CH]-, or BDI, to stabilize the low coordinate divalent tin metal center. Only (BDI)SnN(iPr 2) reacts with phenylacetylene to yield (BDI)SnCCPh, but both species react with methyl triflate to give (BDI)SnOTf and carbon dioxide, resulting in the formation of (BDI)SnOC(O)N(iPr2) and (BDI)SnOC(O)N(H)Ar.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Martyn Coles
Date Deposited: 06 Feb 2012 20:58
Last Modified: 28 Mar 2012 15:35
URI: http://sro.sussex.ac.uk/id/eprint/28952
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