Structural and Catalytic Properties of Bis(guanidine)copper(I) Halides

Oakley, Sarah H, Coles, Martyn P and Hitchcock, Peter B (2003) Structural and Catalytic Properties of Bis(guanidine)copper(I) Halides. Inorganic Chemistry, 42 (10). 3154 - 3156. ISSN 0020-1669

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Abstract

The neutral, bicyclic guanidine 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine (hppH) coordinates to Cu(I) halides via the imine nitrogen, and the complexes are stabilized by intramolecular NX interactions (X = Cl, Br) or are partially dissociated (X = I) in the solid state; in all cases, fluxional behavior is observed in solution. Selected complexes have been tested as catalysts for the polymerization of methyl methacrylate.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Martyn Coles
Date Deposited: 06 Feb 2012 20:55
Last Modified: 19 Mar 2013 14:04
URI: http://sro.sussex.ac.uk/id/eprint/28734
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