Activation and reduction of diethyl ether by low valent uranium: formation of the trimetallic, mixed valence uranium oxo species [U(CpRR)(µ-I)2]3(µ3-O) (CpRR = C5Me5, C5Me4H, C5H4SiMe3)

Larch, Christopher P, Cloke, F Geoffrey N and Hitchcock, Peter B (2008) Activation and reduction of diethyl ether by low valent uranium: formation of the trimetallic, mixed valence uranium oxo species [U(CpRR)(µ-I)2]3(µ3-O) (CpRR = C5Me5, C5Me4H, C5H4SiMe3). Chemical Communications, 44 (1). pp. 82-84. ISSN 1364-548X

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Abstract

The reaction of UI3 and KCpRR' (CpRR' = pentamethylcyclopentadienyl, trimethylsilylcyclopentadienyl or tetramethylcyclopentadienyl) in diethyl ether results in the two-electron reduction of the solvent to form trimetallic, mixed valence uranium oxo species.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science
Depositing User: Geoff Cloke
Date Deposited: 06 Feb 2012 20:54
Last Modified: 02 Jul 2013 12:58
URI: http://sro.sussex.ac.uk/id/eprint/28678
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