The First Example of Simple Oxidative Addition of an Aryl Chloride to a Discrete Palladium (N-Heterocyclic Carbene) Amination Precatalyst

Caddick, Stephen, Cloke, F Geoffrey N, Hitchcock, Peter B, Leonard, John, Lewis, Alexandra K de K, McKerrecher, Darren and Titcomb, Lisa R (2002) The First Example of Simple Oxidative Addition of an Aryl Chloride to a Discrete Palladium (N-Heterocyclic Carbene) Amination Precatalyst. Organometallics, 21 (21). pp. 4318-4319. ISSN 02767333

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Abstract

The oxidative addition of an aryl chloride to a discrete palladium n-heteocyclic carbene amination precatalyst, was discussed. It was found that the oxidative addition of 4-chlorotoluene to Pd(0) resulted in the formation of not a four-coordinate complex but rather the arylated imidazolium salt. The identity of imidazolium salt was confirmed by x-ray crystallography.

Item Type: Article
Additional Information: Additional author: Titcomb, L.R.
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Geoff Cloke
Date Deposited: 06 Feb 2012 20:54
Last Modified: 30 Nov 2012 17:08
URI: http://sro.sussex.ac.uk/id/eprint/28651
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