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The first example of simple oxidative addition of an aryl chloride to a discrete palladium (n-heterocyclic carbene) amination precatalyst

journal contribution
posted on 2023-06-08, 08:11 authored by Stephen Caddick, Geoff Cloke, Peter B Hitchcock, John Leonard, Alexandra K de K Lewis, Darren McKerrecher, Lisa R Titcomb
The oxidative addition of an aryl chloride to a discrete palladium n-heteocyclic carbene amination precatalyst, was discussed. It was found that the oxidative addition of 4-chlorotoluene to Pd(0) resulted in the formation of not a four-coordinate complex but rather the arylated imidazolium salt. The identity of imidazolium salt was confirmed by x-ray crystallography.

History

Publication status

  • Published

Journal

Organometallics

ISSN

02767333

Publisher

ACS Publications

Issue

21

Volume

21

Page range

4318-4319

Pages

2.0

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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