Direct detection of individual bis(arene) rotational isomers in the gas phase by mass-analyzed threshold ionization spectroscopy

Ketkov, Sergey Y, Selzle, Heinrich L and Cloke, F Geoffrey N (2007) Direct detection of individual bis(arene) rotational isomers in the gas phase by mass-analyzed threshold ionization spectroscopy. Angewandte Chemie International Edition, 46 (37). pp. 7072-7074. ISSN 1433-7851

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Abstract

It's a gas! Mass-analyzed threshold ionization (MATI) spectroscopy provides high-resolution ionization potentials and low-energy vibrational frequencies of individual conformers of jet-cooled [(¿6-PhMe)2Cr]. The signals arising from distinct structural isomers were identified on the basis of DFT calculations and comparison of the [(¿6-PhMe) 2Cr] and [(¿6-1,3-Me2C6H 4)(¿6-PhH)Cr] spectra (see picture). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Geoff Cloke
Date Deposited: 06 Feb 2012 20:45
Last Modified: 07 Jun 2012 15:15
URI: http://sro.sussex.ac.uk/id/eprint/27974
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