The synthesis and directed ortho-lithiation of 4-tert-butylsulfinyl[2.2]paracyclophane

Hitchcock, Peter B, Rowlands, Gareth J and Seacome, Richard J (2005) The synthesis and directed ortho-lithiation of 4-tert-butylsulfinyl[2.2]paracyclophane. Organic and Biomolecular Chemistry, 3 (21). pp. 3873-3876. ISSN 1477-0520

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Abstract

The ortho-lithiation of one diastereoisomer of 4-tert-butylsulfinyl[2.2]paracyclophane is the key step to the synthesis of a range of 4,5-disubstituted [2.2]paracyclophane derivatives.

Item Type: Article
Additional Information: Keywords: ASYMMETRIC CATALYSIS; FERROCENE LIGANDS; CHIRAL LIGANDS; DERIVATIVES; REARRANGEMENT
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Richard Seacome
Date Deposited: 06 Feb 2012 20:45
Last Modified: 14 May 2012 15:42
URI: http://sro.sussex.ac.uk/id/eprint/27944
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