Yttrium iodide and bis(trimethylsilyl)methyl complexes of the chelating diamide [ArN(CH2)3NAr]2- (Ar = 2,6-iPr2C6H3)

Cloke, F Geoffrey N, Elvidge, Benjamin R, Hitchcock, Peter B and Lamarche, Vanessa M E (2002) Yttrium iodide and bis(trimethylsilyl)methyl complexes of the chelating diamide [ArN(CH2)3NAr]2- (Ar = 2,6-iPr2C6H3). Journal of the Chemical Society, Dalton Transactions, - (12). pp. 2413-2414. ISSN 1470479X

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Abstract

Yttrium triiodide reacts with the potassium salt K2[ArN-(CH2)3NAr] (Ar = 2,6-iPr2C6H3) to yield a mono-iodide complex and, by further reaction with K[CH(SiMe3)2], the corresponding alkyl complex, which have both been characterised by NMR spectroscopy and X-ray crystallography.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Geoff Cloke
Date Deposited: 06 Feb 2012 20:41
Last Modified: 28 Mar 2012 09:43
URI: http://sro.sussex.ac.uk/id/eprint/27535
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