An Organozinc Hydride Cluster: an Encapsulated Tetrahydrozincate?

Coles, Martyn P, El-Hamruni, Salima M, Smith, J David and Hitchcock, Peter B (2008) An Organozinc Hydride Cluster: an Encapsulated Tetrahydrozincate? Angewandte Chemie International Edition, 47 (52). pp. 10147-10150. ISSN 1433-7851

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Abstract

Reaction of the alkylzinc bromide Zn(C{SiMe3}2{SiMe2hpp})Br (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine) with an excess of sodium hydride gives good yields of an unusual zinc hydride cluster, in which five zinc atoms are linked by (-H) bridges

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Martyn Coles
Date Deposited: 06 Feb 2012 20:40
Last Modified: 07 Jun 2012 15:17
URI: http://sro.sussex.ac.uk/id/eprint/27425
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