1-Triphenylstannyl-2,4,5-tritertiarybutyl-1,3-diphosphole, Ph3SnP2C3But3: Preparation, X-ray crystal structure, theoretical studies and solution fluxional behaviour

Cloke, F Geoffrey N, Hitchcock, Peter B, Nixon, John F, Wilson, D James, Nyulászi, Laszlo and Karpati, Tamas (2005) 1-Triphenylstannyl-2,4,5-tritertiarybutyl-1,3-diphosphole, Ph3SnP2C3But3: Preparation, X-ray crystal structure, theoretical studies and solution fluxional behaviour. Journal of Organometallic Chemistry, 690 (17). 3983 - 3989. ISSN 0022328X

Full text not available from this repository.

Abstract

The 1-triphenylstannyl-2, 4, 5-tritertiarybutyl-1,3-diphosphole, Ph3SnP2C3Bu3t, which has been synthesised from Ph3SnCl and KP2C3Bu3t, has been fully structurally characterised in the solid state but in solution undergoes ready intra-molecular shifts of the Ph3Sn-group around the 1,3-diphospholyl ring. Theoretical calculations concerning both the structure and the dynamic process are presented and discussed.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Geoff Cloke
Date Deposited: 06 Feb 2012 20:37
Last Modified: 28 Mar 2012 08:45
URI: http://sro.sussex.ac.uk/id/eprint/26987
📧 Request an update