Isolation and characterisation ofCs-symmetryC60Me5O2OH, the first methylatedfullerenol; a bis-epoxide with two oxygens in a pentagonal ring

Al-Matar, Hamad, Hitchcock, Peter B, Avent, Anthony G and Taylor, Roger (2000) Isolation and characterisation ofCs-symmetryC60Me5O2OH, the first methylatedfullerenol; a bis-epoxide with two oxygens in a pentagonal ring. Chemical Communications, 12. 1071 - 1072. ISSN 1359-7345

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Abstract

From the reaction between [60]fullerene and MeLi, we have isolated C60Me5O2OH, which has been characterised by both 1H and 13C NMR spectroscopy and by single-crystal X-ray analysis; uniquely, both epoxide groups bridge 5 : 6-bonds in the same pentagon.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: EPrints Services
Date Deposited: 06 Feb 2012 20:34
Last Modified: 25 May 2012 08:19
URI: http://sro.sussex.ac.uk/id/eprint/26733
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