Surprising reactions of a 2H-azaphosphirene complex with a silylene

Ionescu, Emmanuel, Gehrhus, Barbara, Hitchcock, Peter B, Nieger, Martin and Streubel, Rainer (2005) Surprising reactions of a 2H-azaphosphirene complex with a silylene. Chemical Communications, 38 (38). pp. 4842-4844. ISSN 1359-7345

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Abstract

Reaction of the 2H-azaphosphirene complex 1 with the silylene 5 yielded the bicyclic carbene complex 9 as sole product at ambient temperature; the reaction was less selective at elevated temperatures; additionally, the synthesis and structure of the first 1,2,4,3-azadiphosphasilol-5-ene complex 11 is presented.

Item Type: Article
Additional Information: PH solved the crystal structures relevant to this paper and contributed to the mechanistic discussion, part of collaborative project between BG and RS
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: EPrints Services
Date Deposited: 06 Feb 2012 20:30
Last Modified: 12 Jun 2012 12:19
URI: http://sro.sussex.ac.uk/id/eprint/26199
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