UIII-Induced Reductive Co-Coupling of NO and CO to Form UIV Cyanate and Oxo Derivates

Frey, Alistair S P, Cloke, F Geoffrey N, Coles, Martyn P and Hitchcock, Peter B (2010) UIII-Induced Reductive Co-Coupling of NO and CO to Form UIV Cyanate and Oxo Derivates. Chemistry - A European Journal, 16 (31). pp. 9446-9448. ISSN 0947-6539

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Abstract

CO and NO give NCO and O! Sequential treatment of [U(¿-C8H6{SiiPr3-1,4}2)(¿-Cp*)] with CO followed by NO (or vice versa) affords a mixture of the bridging cyanate complex [{U(¿-C8H6{SiiPr3-1,4}2)(¿-Cp*)}2(µ-OCN)2] and the bridging oxo complex [{U(¿-C8H6{SiiPr3-1,4}2)(¿-Cp*)}2(µ-O)], both of which have been structurally characterised (see scheme).

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Alistair Frey
Date Deposited: 06 Feb 2012 20:24
Last Modified: 27 Mar 2012 11:41
URI: http://sro.sussex.ac.uk/id/eprint/25752
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