Tris[\{dimethylamido)dimethylsilyl\}magnesium iodide. A Grignard Reagent without a carbon-magnesium bond?

Eaborn, Colin, Farook, Adam, Hitchcock, Peter and Smith, David J (1997) Tris[\{dimethylamido)dimethylsilyl\}magnesium iodide. A Grignard Reagent without a carbon-magnesium bond? Organometallics, 16. pp. 503-504.

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Abstract

Reaction of (Me2NMe2Si)3CI with Mg gives the Grignard reagent (Me2NMe2Si)3CMgI, in which all three N atoms are coordinated to Mg and there is a planar carbanionic center, suggesting the absence of Mg bonding.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: David Smith
Date Deposited: 06 Feb 2012 20:09
Last Modified: 19 Mar 2013 14:00
URI: http://sro.sussex.ac.uk/id/eprint/24337
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