Syntheses, structural studies, photoelectron spectra and density functional theory calculations of the "pseudo" tetraphospha-metallocenes [M(eta-P2C3Bu3t)(2)], (M = Ni, Pd, Pt)

Cloke, F Geoffrey N, Green, Jennifer C, Hitchcock, Peter B, Nixon, John F, Suter, James L and Wilson, D James (2009) Syntheses, structural studies, photoelectron spectra and density functional theory calculations of the "pseudo" tetraphospha-metallocenes [M(eta-P2C3Bu3t)(2)], (M = Ni, Pd, Pt). Dalton Transactions (7). pp. 1164-1171. ISSN 1477-9226

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Abstract

Syntheses and structural characterization of the complexes [M(eta-P2C3Bu3t)(2)], (M = Ni, Pd, Pt) are described. The nickel compound has an 18-electron [Ni(eta(5)-P2C3Bu3t)(eta(3)-P2C3Bu3t)] structure, whereas the palladium and platinum compounds both have a 16-electron [M(eta(3)-P2C3Bu3t)(2)] structure (M = Pd, Pt). The electronic structure is examined and discussed using both photoelectron spectroscopy and DFT calculations.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Geoff Cloke
Date Deposited: 06 Feb 2012 20:06
Last Modified: 13 Jun 2012 13:20
URI: http://sro.sussex.ac.uk/id/eprint/24094
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