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Syntheses, structural studies, photoelectron spectra and density functional theory calculations of the "pseudo" tetraphospha-metallocenes [M(eta-P2C3Bu3t)(2)], (M = Ni, Pd, Pt)

journal contribution
posted on 2023-06-08, 05:01 authored by Geoff Cloke, Jennifer C Green, Peter B Hitchcock, John F Nixon, James L Suter, D James Wilson
Syntheses and structural characterization of the complexes [M(eta-P2C3Bu3t)(2)], (M = Ni, Pd, Pt) are described. The nickel compound has an 18-electron [Ni(eta(5)-P2C3Bu3t)(eta(3)-P2C3Bu3t)] structure, whereas the palladium and platinum compounds both have a 16-electron [M(eta(3)-P2C3Bu3t)(2)] structure (M = Pd, Pt). The electronic structure is examined and discussed using both photoelectron spectroscopy and DFT calculations.

History

Publication status

  • Published

Journal

Dalton Transactions

ISSN

1477-9226

Publisher

Royal Society of Chemistry

Issue

7

Page range

1164-1171

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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