The first structurally charcterised solvent-free sigma -bonded diorganocalcium Ca[C(SiMe 3 ) 3 ] 2

Eaborn, Colin, Hawkes, Simon A, Hitchcock, Peter B and Smith, J David (1997) The first structurally charcterised solvent-free sigma -bonded diorganocalcium Ca[C(SiMe 3 ) 3 ] 2. Chemical Communications, 20. 1961 - 1962. ISSN 1359-7345

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Abstract

The monomeric solvent-free compound CaR2 1
[R = C(SiMe3)3] is obtained as colourless air- and moisturesensitive
crystals from the reaction between KR and CaI2; in
the solid the C–Ca–C axis is bent with Ca–C 2.459(9) Å and
C–Ca–C 149.7(6)°; reactions of 1 with ethers ROEt give RH,
ethene and Ca(OEt)2.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: David Smith
Date Deposited: 06 Feb 2012 19:49
Last Modified: 06 Jun 2013 14:19
URI: http://sro.sussex.ac.uk/id/eprint/22330
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