Study on the interaction between tetracene and Cu(110) surface

Dou, Weidong, Li, Nana, Guan, Dandan, Song, Fei, Huang, Han, Zhang, Hanjie, Li, Haiyang, He, Pimo, Bao, Shining, Chen, Qiao and Zhou, Wuzong (2007) Study on the interaction between tetracene and Cu(110) surface. Journal of Chemical Physics, 127 (22). ISSN 0021-9606

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Abstract

The electronic structure of tetracene on Cu (110) surface has been studied by using ultraviolet photoemission spectroscopy (UPS). The emission features from the organic molecule are located from 1 to 10 eV below the Fermi level, and they shift in binding energy with increasing the coverage of the organic material. For the surface with multilayer of tetracene, six well-resolved features were found at 1.90, 3.40, 4.70, 5.95, 6.95, and 9.15 eV below the Fermi level, respectively. On the surface with a lower coverage of tetracene, angle-resolved UPS measurements suggest that the molecular plane is parallel to the substrate. Density functional theory calculation confirms the flat-lying adsorption mode and shows that the tetracene molecule prefers to be adsorbed on the long bridge site with its long axis in the [1(1)over bar 0] azimuth.

Item Type: Article
Additional Information: Article Number: 224709
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: EPrints Services
Date Deposited: 06 Feb 2012 19:38
Last Modified: 01 May 2012 14:40
URI: http://sro.sussex.ac.uk/id/eprint/21638
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