Coordination Chemistry of Isomeric Mixtures of Linked Di(phosphaguanidine) Compounds; a Spectroscopic and Crystallographic Study

Mansfield, Natalie E, Coles, Martyn P, Avent, Anthony G and Hitchcock, Peter B (2006) Coordination Chemistry of Isomeric Mixtures of Linked Di(phosphaguanidine) Compounds; a Spectroscopic and Crystallographic Study. Organometallics, 25 (10). 2470 - 2474. ISSN 0276-7333

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Abstract

Multinuclear NMR spectroscopy and X-ray diffraction techniques have been used to identify diastereomeric mixtures of rac- and meso-di(phosphaguanidine) compounds. A brief survey of their coordination chemistry has demonstrated the formation of N,N'-bound bimetallic aluminum species and monometallic platinum complexes in which the ligand chelates to the metal through the two phosphorus donor atoms.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Natalie Emma Mansfield
Date Deposited: 06 Feb 2012 19:38
Last Modified: 23 Mar 2012 12:30
URI: http://sro.sussex.ac.uk/id/eprint/21604
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