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Metal Complexes of Guanidine-Substituted Alkyl Ligands: An Unsolvated Monomeric Two-Coordinate Organolithium

journal contribution
posted on 2023-06-07, 23:33 authored by Martyn P Coles, Sebnem E. Sozerli, J David Smith, Peter B Hitchcock
Single-crystal X-ray diffraction of MC(SiMe3)2(SiMe2hpp) (M = Li, K; hppH = 1,3,4,6,7,8,-hexahydro-2H-pyrimido[1,2-a]pyrimidine) showed nonsolvated organometallic compounds in which the iminonitrogen of the guanidine forms strong intramolecular bonds to generate six-membered metallacycles.

History

Publication status

  • Published

Journal

Organometallics

ISSN

02767333

External DOI

Issue

27

Volume

26

Page range

6691-6693

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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