Metal Complexes of Guanidine-Substituted Alkyl Ligands: An Unsolvated Monomeric Two-Coordinate Organolithium

Coles, Martyn P, Sozerli, Sebnem E., Smith, J David and Hitchcock, Peter B (2007) Metal Complexes of Guanidine-Substituted Alkyl Ligands: An Unsolvated Monomeric Two-Coordinate Organolithium. Organometallics, 26 (27). pp. 6691-6693. ISSN 02767333

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Abstract

Single-crystal X-ray diffraction of MC(SiMe3)2(SiMe2hpp) (M = Li, K; hppH = 1,3,4,6,7,8,-hexahydro-2H-pyrimido[1,2-a]pyrimidine) showed nonsolvated organometallic compounds in which the iminonitrogen of the guanidine forms strong intramolecular bonds to generate six-membered metallacycles.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Martyn Coles
Date Deposited: 06 Feb 2012 19:37
Last Modified: 23 Mar 2012 12:02
URI: http://sro.sussex.ac.uk/id/eprint/21528
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