Unusual generation of methoxy groups in Barton deoxygenations of alcohols

Bensasson, Caroline S, Cornforth, Sir John, Du, Ming-Hui and Hanson, James R (1997) Unusual generation of methoxy groups in Barton deoxygenations of alcohols. Chemical Communications, 16. pp. 1509-1510. ISSN 1359-7345

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Abstract

Reaction of the S-methyl dithiocarbonate of lanosterol with excess of tributyltin deuteride and azoisobutyronitrile in benzene afforded lanosteryl methyl ether in which all hydrogen in the methoxy group originated from the organotin reagent.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: James Hanson
Date Deposited: 06 Feb 2012 19:32
Last Modified: 20 Sep 2012 13:17
URI: http://sro.sussex.ac.uk/id/eprint/21103
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