File(s) not publicly available
The first delocalized phosphole containing a planar tricoordinate phosphorus atom: 1-[bis(trimethylsilyl)methyl]-3,5-bis(trimethylsilyl)-1,2,4-triphosphole
journal contribution
posted on 2023-06-07, 23:02 authored by Geoff Cloke, Peter B Hitchcock, Philip Hunnable, John F Nixon, Laszlo Nyulászi, Edgar Niecke, Vera ThelenThe sterically demanding groups on the tricoordinate phosphorus atom, the pi-electron acceptors substituted on the ring, and the dicoordinate phosphorus atoms within the ring are the most significant factors contributing to the planarity and aromaticity of the 1,2,4-triphosphole ring in 1. The Bird aromaticity index for 1 shows that it has the most pronounced aromatic character of all known phospholes.
History
Publication status
- Published
Journal
Angewandte Chemie International EditionISSN
1433-7851Issue
8Volume
37Page range
1083-1086Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
Categories
No categories selectedKeywords
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC