[60]- and [70]Fullerenes are trifluoromethylated across 5 : 6-bonds

Darwish, Adam D, Avent, Anthony G, Abdul-Sada, Ala'a K and Taylor, Roger (2003) [60]- and [70]Fullerenes are trifluoromethylated across 5 : 6-bonds. Chemical Communications, 21 (12). pp. 1374-1375. ISSN 1359-7345

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Trifluoromethylation of[60]- and [70]fullerenes occurs across both 6:6- and 5: 6- bonds giving unsymmetrical tetramethyl adducts having four contiguous CF3 groups; both fullerenes give bis adducts which do not involve 6: 6-addition, and unsymmetrical hexa-adducts (with contiguous CF3 groups) are also obtained from [60] fullerene.

Item Type: Article
Additional Information: AAS performed the MS measurements in collaboration with the late RT and co-authored the paper
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Adam Darwish
Date Deposited: 06 Feb 2012 19:20
Last Modified: 12 Jun 2012 12:20
URI: http://sro.sussex.ac.uk/id/eprint/20187
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