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Titanium and niobium imido complexes derived from diamidoamine ligands
journal contribution
posted on 2023-06-07, 21:59 authored by Philip E Collier, Stephen M Pugh, Howard S C Clark, Jason B Love, Alexander J Blake, Geoff Cloke, Philip MountfordNew groups 4 and 5 imido complexes derived from the diamidoamine ligand Me3SiN(CH2CH2NSiMe3)2 (N2N) are described. Reactions of Li2[N2N] with [Ti(NR)Cl2(py)3] gave compound 1 in which the N2N ligand adopts a fac-coordination mode. With [Nb(N1-Bu)Cl3(py)2], two different Nb(V) products were formed.
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Publication status
- Published
Journal
Inorganic ChemistryISSN
00201669External DOI
Issue
9Volume
39Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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