Titanium and niobium imido complexes derived from diamidoamine ligands

Collier, Philip E, Pugh, Stephen M, Clark, Howard S C, Love, Jason B, Blake, Alexander J, Cloke, F Geoffrey N and Mountford, Philip (2000) Titanium and niobium imido complexes derived from diamidoamine ligands. Inorganic Chemistry, 39 (9). ISSN 00201669

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Abstract

New groups 4 and 5 imido complexes derived from the diamidoamine ligand Me3SiN(CH2CH2NSiMe3)2 (N2N) are described. Reactions of Li2[N2N] with [Ti(NR)Cl2(py)3] gave compound 1 in which the N2N ligand adopts a fac-coordination mode. With [Nb(N1-Bu)Cl3(py)2], two different Nb(V) products were formed.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Geoff Cloke
Date Deposited: 06 Feb 2012 19:05
Last Modified: 30 Nov 2012 17:02
URI: http://sro.sussex.ac.uk/id/eprint/19258
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