Photosolvolysis reactions of 3-alkoxypyridinium tetraflouroborate salts

Penkett, Clive S and Simpson, Iain D (1999) Photosolvolysis reactions of 3-alkoxypyridinium tetraflouroborate salts. Tetrahedron, 55. 6183 - 6204.

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Abstract

Irradiation of a series of 3-alkoxypyridinium tetrafluoroborate salts in alcohol solution resulted in the formation of cyclopentenone ketals by diastereoselective incorporation of the alcohol solvent under the basic conditions of the photolysis reaction. In a second series of photochemical reactions, the same 3-alkoxypyridinium salts were irradiated in water to yield β-hydroxycyclopentanones stereoselectively.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Clive Penkett
Date Deposited: 06 Feb 2012 18:41
Last Modified: 19 Mar 2012 12:44
URI: http://sro.sussex.ac.uk/id/eprint/17731
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