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A Novel Organolead(II) Species the Plumbacycloalkane Derivative [CH2SiMe2C(SiMe3)2PbC(SiMe3)2SiMe2Ch2]
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posted on 2023-06-07, 20:21 authored by Colin Eaborn, Tomasz Ganicz, Peter B Hitchcock, J David Smith, S E SozerliThe title lead(II) derivative was obtained as dark blue crystals by treatment of PbCl2 with (TMEDA = N,N,N‘,N‘-tetramethylethylenediamine) in tetrahydrofuran and its structure determined by X-ray diffraction. The compound is in effect the first dialkylead(II) species to be structurally characterized. The C-Pb-C angle is 117.1(2)°. Analogous treatment of SnCl2 yielded a yellow solid, which was judged from spectroscopic data to be the TMEDA complex of the analogous stannacycloalkane.
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- Published
Journal
OrganometallicsPublisher
OrganometallicsVolume
16Page range
5621 - 5622ISBN
0276-7333Department affiliated with
- Chemistry Publications
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- No
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- Yes
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2012-02-06Usage metrics
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