A Novel Organolead(II) Species the Plumbacycloalkane Derivative [CH2SiMe2C(SiMe3)2PbC(SiMe3)2SiMe2Ch2]

Eaborn, Colin, Ganicz, Tomasz, Hitchcock, Peter B, Smith, J David and Sozerli, S E (1997) A Novel Organolead(II) Species the Plumbacycloalkane Derivative [CH2SiMe2C(SiMe3)2PbC(SiMe3)2SiMe2Ch2]. Organometallics, 16. 5621 - 5622.

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Abstract

The title lead(II) derivative was obtained as dark blue crystals by treatment of PbCl2 with (TMEDA = N,N,N‘,N‘-tetramethylethylenediamine) in tetrahydrofuran and its structure determined by X-ray diffraction. The compound is in effect the first dialkylead(II) species to be structurally characterized. The C−Pb−C angle is 117.1(2)°. Analogous treatment of SnCl2 yielded a yellow solid, which was judged from spectroscopic data to be the TMEDA complex of the analogous stannacycloalkane.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: David Smith
Date Deposited: 06 Feb 2012 18:30
Last Modified: 30 Nov 2012 17:00
URI: http://sro.sussex.ac.uk/id/eprint/16876
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