Syntheses of the novel cage compounds P3Se3C3But3 and P3Se4C3But3 and an unusual insertion reaction of [PtCl2(PMe3)] into the Se-Se bond of the latterto give the six-coordinate Pt(IV) complex [PtCl2(PMe3)P3Se4C3But3]

Hitchcock, Peter B, Nixon, John F and Sakarya, Nurgun (2000) Syntheses of the novel cage compounds P3Se3C3But3 and P3Se4C3But3 and an unusual insertion reaction of [PtCl2(PMe3)] into the Se-Se bond of the latterto give the six-coordinate Pt(IV) complex [PtCl2(PMe3)P3Se4C3But3]. Chemical Communications, 18. 1745 - 1746. ISSN 1359-7345

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Abstract

The novel cage compounds P3Se3C3But3 and P3Se4C3But3 are formed (together with the 1,2,4-selenadiphosphole P2SeC2But2) from the reaction of the phosphaalkyne ButCP with selenium; the [PtCl2(PMe3)] fragment undergoes an unusual insertion reaction into the Se–Se bond of P3Se4C3- But3.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: John Nixon
Date Deposited: 06 Feb 2012 18:26
Last Modified: 25 May 2012 08:22
URI: http://sro.sussex.ac.uk/id/eprint/16335
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