On the structure of liquid hydrogen fluoride

McLain, Sylvia E, Benmore, Chris J, Siewenie, Joan E, Urquidi, Jacob and Turner, John F C (2004) On the structure of liquid hydrogen fluoride. Angewandte Chemie International Edition, 43 (15). pp. 1952-1955. ISSN 1433-7851

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Abstract

Short, bent, strongly hydrogen-bonded chains, with strong interchain interactions and very little branching are the basis of the structure of liquid hydrogen fluoride (see picture), as determined at the partial radial distribution function level.

Item Type: Article
Additional Information: First determination of the structure of hydrogen fluoride at the atomic pair level, using neutron and high energy X-ray diffraction which showed that, contrary to calculations the structure is composed of finite chains, with an exceptionally short bent intermolecular hydrogen bond. JFCT directed the work and is corresponding author.
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: John Turner
Date Deposited: 06 Feb 2012 18:22
Last Modified: 16 Mar 2012 15:28
URI: http://sro.sussex.ac.uk/id/eprint/15998
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