Spontaneous assembly of a nine-vertex lithium framework encapsulating the peroxide dianion

Coles, Martyn P and Hitchcock, Peter B (2005) Spontaneous assembly of a nine-vertex lithium framework encapsulating the peroxide dianion. Chemical Communications, 25. 3165 - 3167. ISSN 1359-7345

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Abstract

Investigation of the structure of the lithiated bicyclic guanidine 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine (hppH) has led to the reproducible isolation of compounds containing the 'Li-9(hpp)(7)(O-2)' core, in which a peroxide dianion has been encapsulated within a mono-capped, cubic array of lithium ions.

Item Type: Article
Additional Information: MPC performed all synthetic work and is the corresponding author. The first time the peroxo-dianion has been encapsulated by lithium rather than forming oxide species. The first demonstration of larger interstitial ions within simple lithium-guanidinate cages.
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Martyn Coles
Date Deposited: 06 Feb 2012 18:19
Last Modified: 16 Mar 2012 14:15
URI: http://sro.sussex.ac.uk/id/eprint/15746
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