Synthetic and structural studies on amine coordination to Pd-N-heterocyclic carbene complexes

Lewis, Alexandra k de k, Caddick, Stephen, Esposito, Oriana, Cloke, F Geoffrey N and Hitchcock, Peter B (2009) Synthetic and structural studies on amine coordination to Pd-N-heterocyclic carbene complexes. Dalton Transactions, 35. pp. 7094-7098. ISSN 1477-9226

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Abstract

The reaction between 2-chlorobenzylamine or 2-chlorobenzylalcohol and Pd((IBu)-Bu-t)(2) ((IBu)-Bu-t = 1,3-di-tert-butylimidazol-2-ylidene) in benzene affords the dimeric complexes [Pd((IBu)-Bu-t)(mu-NH{2-CH2C6H4})](2) and [Pd((IBu)-Bu-t)(mu-O{2-CH2C6H4})](2); the latter has been structurally characterised. The syntheses, structural characterisation and reactivity of the Pd-NHC amine complexes [(ItBu)Pd(R-4-C6H4)(morpholine)Cl] (R = Me, OMe, CO2Me), intermediates in the Buchwald-Hartwig aryl amination reaction, are also reported.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Oriana Esposito
Date Deposited: 06 Feb 2012 18:17
Last Modified: 13 Jun 2012 13:22
URI: http://sro.sussex.ac.uk/id/eprint/15577
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